Crystal structure of iso-propylcyclopentadienylchloro-(bistriphenylphosphine) ruthenium

Authors
Jin, JT Huang, JL Qian, YL Zhu, GY Jia, YS Huang, QC
Citation
Jt. Jin et al., Crystal structure of iso-propylcyclopentadienylchloro-(bistriphenylphosphine) ruthenium, CHIN J ST C, 19(1), 2000, pp. 35-38
Citations number
3
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
02545861 → ACNP
Volume
19
Issue
1
Year of publication
2000
Pages
35 - 38
Database
ISI
SICI code
0254-5861(2000)19:1<35:CSOI>2.0.ZU;2-1
Abstract
Crystal of the title complex, C44H41ClP2Ru, belongs to monoclinic system, s pace group P2(1)/n, a = 11.968 (2), 16 = 17.721(2), c = 17.322(2) Angstrom, beta = 97.669 (12)degrees, V = 3640.8 (9) Angstrom(3), M-r = 768.2, Z = 4, D-c = 1.402 g. cm(-3), mu = 5.217 mm(-1), F(000) = 1584, the final R = 0.0 418 and R-w = 0.0551 for 3734 observed reflections (F > 3.9 sigma(F)). The geometry around the ruthenium can be considered as a distorted tetrahedron, The electronic and steric effects of iso-propyl substituent on the structu re of the title complex(I) are discussed.