Electroosmotic flow rates through porous media are predicted through the cy
lindrical and annular geometrical models. Differences in the results obtain
ed from the two models are compared and discussed by making reference to th
e electrokinetic remediation of contaminated soil. In the annular-model cas
e, when the electrical potential on the outer wall is less than on the inne
r wall and/or the double-layer thickness is much shorter than the outer rad
ius, a maximum flux is predicted at some outer-to-inner-radii ratio. At a g
iven soil porosity, the cylindrical model predicts a higher flow rate than
the annular model, and the: difference becomes increasingly more pronounced
as the radii ratio approaches unity, which corresponds to a low-porosity s
oil. (C) 2000 Elsevier Science B.V. All rights reserved.