Crystal structure of new potassium-barium decavanadate

Authors
Rastsvetaeva, RK
Citation
Rk. Rastsvetaeva, Crystal structure of new potassium-barium decavanadate, CRYSTALLO R, 44(6), 1999, pp. 958-959
Citations number
3
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTALLOGRAPHY REPORTS
ISSN journal
10637745 → ACNP
Volume
44
Issue
6
Year of publication
1999
Pages
958 - 959
Database
ISI
SICI code
1063-7745(199911/12)44:6<958:CSONPD>2.0.ZU;2-1
Abstract
The structure of a new decavanadate of the composition K2Ba2V10O28. 8H(2)O has been solved by direct methods (3800 reflections) up to R = 0.035 withou t the preliminary data on its exact composition. The V5+-ions form distorte d octahedra, which, in turn, form polyhedral clusters linked by large potas sium and barium cations and water molecules.