Hydrofluoride-based electrolytes with proton conduction have been successfu
lly used in intermediate: temperature fuel cell applications. Among the var
ious hydrofluoride electrolytes, LiF-CaH2 and its composite with Al2O3, i.e
., LiF-CaH2-Al2O3, are the most promising candidates which show more advant
ages than the other hydrofluorides. In this communication, we put our empha
sis on the LiF-CaH2-Al2O3 electrolytes and their applications for intermedi
ate temperature fuel cells. Furthermore, new fuel cell processes from hydri
de ions, H-, and the electrochemical behaviour of LiF-CaH2-Al2O3 electrolyt
es and fuel cells are discussed in more detail. (C) 2000 Elsevier Science S
.A. All rights reserved.