Electrochromic properties of new methacrylate copolymers containing pendant oligothiophene and oligo(ethyleneoxide) moieties in the presence of a polymer-gel electrolyte
Y. Ohsedo et al., Electrochromic properties of new methacrylate copolymers containing pendant oligothiophene and oligo(ethyleneoxide) moieties in the presence of a polymer-gel electrolyte, ELECTR ACT, 45(8-9), 2000, pp. 1543-1547
Electrochromic properties of new methacrylate copolymers containing pendant
terthiophene and oligo(ethyleneoxide) moieties, poly[(2,2':5',2 "-terthiop
hen-5-yl)methyl methacrylate-co-alpha-ethoxy-omega-methacryloyl-oligo(ethyl
eneoxide)] (poly(MA3T-co-MAEO)), in the presence of a polymer-gel electroly
te were studied. A polymer-gel electrolyte composed of poly(methylmethacryl
ate), lithium perchlorate, and propylene carbonate was sandwiched between t
wo indium-tin oxide (ITO)-coated glass substrates, on one of which a film o
f poly(MA3T-co-MAEO) was coated. The device was found to undergo a color ch
ange from yellowish-orange to pale green and vice versa on electrochemical
oxidation and reduction. The response times for green coloration and decolo
ration of a poly(MA3Tco-MAEO) 60/40 film in the presence of the polymer-gel
electrolyte were estimated to be 5.3 and 5.5 s, respectively. (C) 2000 Els
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