Microwave-assisted rapid incorporation of ruthenium into lacunary keggin-type polyoxotungstates: One-step synthesis, Ru-99, W-183 NMR characterization and catalytic activity of [PW11O39RuII(DMSO)](5-)
A. Bagno et al., Microwave-assisted rapid incorporation of ruthenium into lacunary keggin-type polyoxotungstates: One-step synthesis, Ru-99, W-183 NMR characterization and catalytic activity of [PW11O39RuII(DMSO)](5-), EUR J INORG, (1), 2000, pp. 17-20
Microwave irradiation for 15 minutes allowed the highly selective hydrother
mal synthesis of the diamagnetic, air-stable oxidation catalyst [PW11O39RuI
I(DMSO)](5-), as confirmed by H-1, P-31, Ru-99 and W-183 NMR techniques.