The bosonisation technique is used to calculate the resonant Raman spectrum
of a quantum wire with two electronic sub-hands occupied. Close to resonan
ce, the cross-section at frequencies in the region of the inter-sub-band tr
ansitions shows distinct peaks in parallel polarisation of the incident and
scattered light that. are signature of collective higher-order spin densit
y excitations. This is in striking contrast to the conventional selection r
ule for non-resonant Raman scattering according to which spin modes can app
ear only in perpendicular polarisation, We predict a new selection rule for
the. excitations observed near resonance, namely that. apart from charge d
ensity excitations, only spin modes with positive group velocities can appe
ar as peaks in the spectra in parallel configuration close to resonance. Th
e results are consistent with all of the presently available experimental d
ata.