The purpose of this study was to identify the main phenolic compounds prese
nt in an olive leaf extract (OL) in order to delineate the differential ant
ioxidant activities of these compounds through the extent of their abilitie
s to scavenge the ABTS(.+) radical cation and to clarify the structural ele
ments conferring antioxidant capacity in aqueous systems. The results show
that the relative abilities of the flavonoids from olive leaf to scavenge t
he ABTS(.+) radical cation are influenced by the presence of functional gro
ups in their structure, mainly the B-ring catechol, the 3-hydroxyl group an
d the 2,3-double bond conjugated with the 4-oxo function. For the other phe
nolic compounds present in OL, their relative abilities to scavenge the ABT
S(.+) radical cation are mainly influenced by the number and position of fr
ee hydroxyl groups in their structure. Also, both groups of compounds show
synergic behaviour when mixed, as occurs in the OL. (C) 2000 Elsevier Scien
ce Ltd. All rights reserved.