The non-linear response of fluorescein-doped boric acid glass was prob
ed using the Z-scan technique. A striking contrast was observed in its
non-linear transmission characteristics at different argon-ion laser
wavelengths. The non-linear transmission characteristics exhibit stron
g saturation behaviour at 457.9 nm whilst at 476.5 nm and 488.0 nm the
response is dominated by intense excited state absorption. The experi
mental observations are explained using the four-level saturable absor
ber model. The excited state absorption cross-section, saturation inte
nsity, light induced absorption and refraction changes have been deter
mined along with the sign of the non-linearity at various argon laser
wavelengths. The optical limiting characteristics of fluorescein at 47
6.5 nm and 457.9 nm are also reported. The behaviour of the sample was
in agreement with the Z-scan observations.