Synthesis of difurazanyl Ethers from 4,4 '-dinitroazoxyfurazan

Authors
Sheremetev, AB Aleksandrova, NS Melnikova, TM Novikova, TS Strelenko, YA Dmitriev, DE
Citation
Ab. Sheremetev et al., Synthesis of difurazanyl Ethers from 4,4 '-dinitroazoxyfurazan, HETEROAT CH, 11(1), 2000, pp. 48-56
Citations number
32
Categorie Soggetti
Chemistry
Journal title
HETEROATOM CHEMISTRY
ISSN journal
10427163 → ACNP
Volume
11
Issue
1
Year of publication
2000
Pages
48 - 56
Database
ISI
SICI code
1042-7163(2000)11:1<48:SODEF4>2.0.ZU;2-S
Abstract
Nonselective attacks at the carbon bonded to a nitro group and carbon bonde d to the N(O) atom of the azoxy group were observed in the reactions of 4,4 '-dinitroazoxyfurazan with bases and nucleophiles. A mechanism is presented to account for both of the pathways to products. A series of new difurazan yl ether derivatives was synthesized. (C) 2000 John Wiley & Sons, Inc.