J. Gomez-bueso et al., Composites made from acetylated lignocellulosic fibers of different originPart I. Properties of dry-formed fiberboards, HOLZ ROH WE, 57(6), 1999, pp. 433-438
Lignocellulosic fibers of different origins were acetylated in large batche
s. The fibers used were of commercial, medium density fiberboard (MDF) pulp
quality produced from softwood, beech, waste wood (low quality residue fro
m an intermediate forest cutting) and wheat straw, respectively. Fiber from
de-inked, semi-bleached, recycled paper was also included in the study. La
boratory fiberboards were produced from the acetylated fibers by using powd
ered phenolic resin of the novolak type as a binding agent. Control boards
made from unmodified fiber were also produced. The fiberboards were subject
ed to mechanical and dimensional stability testing. The acetylation of the
fiber, regardless of the source of the lignocellulosic material, has a very
positive impact on the performance of fiber composite products. For instan
ce, the thickness swelling for softwood fiberboard in water is reduced by a
pproximately 90%, and the mechanical properties are slightly improved. Resu
lts from cyclic testing according to EN 321, (three cycles, each comprising
72 h water immersion, 24 h freezing at -18 degrees C and 72 h drying at 70
degrees C) show that more than 90% of the internal bond strength, IBS, rem
ained after the testing. This value can be compared with the corresponding
value of 30-40% obtained for fiberboards made from unmodified fibers. The r
emaining thickness swelling of fiberboards made from acetylated fibers was
independent of fiber source and resin content. The results obtained showed
that acetylation can improve the mechanical properties of fiberboards provi
ded that a proper resin is chosen.