TITANOCENE(II)-PROMOTED REACTION OF THIOACETALS WITH ALKYNES - HIGHLYSTEREOSELECTIVE PREPARATION OF CONJUGATED DIENES

Authors
TAKEDA T SHIMOKAWA H MIYACHI Y FUJIWARA T
Citation
T. Takeda et al., TITANOCENE(II)-PROMOTED REACTION OF THIOACETALS WITH ALKYNES - HIGHLYSTEREOSELECTIVE PREPARATION OF CONJUGATED DIENES, Chemical communications, (11), 1997, pp. 1055-1056
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
11
Year of publication
1997
Pages
1055 - 1056
Database
ISI
SICI code
1359-7345(1997):11<1055:TROTWA>2.0.ZU;2-J
Abstract
The reaction of organotitanium species, prepared by the desulfurizativ e titanation of thioacetals using (C5H5)(2)Ti- [P(OEt)(3)](2), with al kynes gives conjugated dienes in good yields with high stereoselectivi ty.