MECHANISTIC STUDY ON MESO-HYDROXYOCTAETHYLPORPHYRIN FORMATION FROM ANFE-III(OEP)-H2O2 COMPLEX

Authors
TAJIMA K TADA K SHIGEMATSU M KANAORI K AZUMA N MAKINO K
Citation
K. Tajima et al., MECHANISTIC STUDY ON MESO-HYDROXYOCTAETHYLPORPHYRIN FORMATION FROM ANFE-III(OEP)-H2O2 COMPLEX, Chemical communications, (11), 1997, pp. 1069-1070
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
11
Year of publication
1997
Pages
1069 - 1070
Database
ISI
SICI code
1359-7345(1997):11<1069:MSOMFF>2.0.ZU;2-2
Abstract
The benzoyl ester of an. iron(III) meso-hydroxyoctaethyl-porphyrin com plex, containing O-18 derived from molecular oxygen, is isolated from the reaction solution of the complex [Fe-III(oep)(OOH)(OH)](-) which i s prepared by reduction of [Fe-II(oep)(py)(O-18(2))] with sodium ascor bate.