Crystal and molecular structure of dibromamine-T

Authors
Yathirajan, HS Rangappa, KS Nagendra, P Mohana, KN Sridhar, MA Lokanath, NK Prasad, JS
Citation
Hs. Yathirajan et al., Crystal and molecular structure of dibromamine-T, I J CHEM A, 38(11), 1999, pp. 1169-1172
Citations number
18
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
38
Issue
11
Year of publication
1999
Pages
1169 - 1172
Database
ISI
SICI code
0376-4710(199911)38:11<1169:CAMSOD>2.0.ZU;2-9
Abstract
The crystal structure of dibromamine-T, an important brominating/oxidising agent, which crystallizes in the monoclinic space group P2(1)/c with cell p arameters a = 10.325(3)Angstrom, b = 8.281(2)Angstrom, c = 12.611(5)Angstro m, beta = 102.44(3)degrees and Z = 4 has been solved using DIRDIF programme and refined using SHELXL. The structure shows both intramolecular and inte rmolecular hydrogen bonds of the type CH....O. The molecules are arranged i n layers.