ELECTRON-ATTACHMENT TO A NEGATIVE-ION - E-84(-)REVERSIBLE-ARROW-C-84(-2)(C)

The observation of sequential attachment of two electrons to the C-84 molecule and the subsequent autodetachment of the C-84 dianion is repo rted. Remarkably, the cross section for attaching the second electron is estimated to be of the same order as that for adding the first elec tron. The measured lifetime for autodetachment of C-84(-2) (similar to 60 mu sec) is in accord with calculations assuming ''thermionic emiss ion'' from the vibrationally hot dianion. The first (EA(1)) and second (EA(2)) electron affinities of the two low-lying D-2 and D-2d isomers of C-84 are calculated using density functional theory to be +3.14 an d +0.44 eV, respectively.