There are many controversies about the long-term prognosis of hydroxyapatit
e (HA)-coated implants. Failure mag be related to compositional and structu
ral changes of the coating occurring during implantation. Two retrieved and
two unused HA-coated blade-type implants were examined by stereomicroscopy
, secondary electron microscopy, Fourier transform infrared spectroscopy, X
-ray diffraction, and electron probe microanalysis. The objective was to in
vestigate the HA morphology, composition, and structure, and to characteriz
e the changes that occurred in the retrieved implant coatings. Retrieved im
plants presented partial Loss of the coating, especially at the apical and
mesiodistal edges. Remaining HA was thick and Battened in the cervical and
central areas and gradually thinner and rougher towards the apical and mesi
odistal edges. Increase of CI and Mg, decrease of OH, and X-ray diffraction
peak broadening mere found in the retrieved implant coatings, in compariso
n with the unused implants. Morphological changes of the retrieved implants
seem to depend on stress values in the surrounding bone and on implant mob
ility, Compositional changes and increased amount of lattice imperfections
appeared in the retrieved implant coatings, as a result of ion substitution
s in the apatite lattice. However, the present study could not confirm the
influence of these changes on implant failure. (C) 2000 John Wiley & Sons,
Inc.