A. Laaksonen et al., Upper tropospheric SO2 conversion into sulfuric acid aerosols and cloud condensation nuclei, J GEO RES-A, 105(D1), 2000, pp. 1459-1469
We have investigated the potential of upper tropospheric cloud condensation
nuclei (CCN) formation hom sulfur dioxide, This process involves three ste
ps including SO2 conversion to gaseous sulfuric acid (GSA), homogeneous bim
olecular nucleation of GSA and water vapor leading to new aerosol particles
, and new aerosol particle growth via mutual coagulation and GSA-H2O conden
sation. Our investigation includes both measurements of SO2 and GSA as well
as model calculations of SO2 conversion to new aerosol particles ill the p
resence of preexisting aerosols which act as a competing sink for GSA, The
model reproduces the measured abundance ratio GSA-SO2 reasonably well. Furt
hermore, the model predicts that efficient upper tropospheric CCN formation
from SO2 may, in fact, occur under certain plausible conditions. These con
ditions are explored utilizing the factor F-CCN: defined as a ratio of the
source and sink terms of gaseous sulfuric acid. In particular, a threshold
F-CCN value for efficient CCN formation is calculated with the model.