Thin sea ice plays a central role in the surface heat and mass balance of t
he Arctic Ocean. In order to develop understanding of these-balances we des
cribe and analyze highly resolved temperature data taken through the air/se
a/ice interface during the transition from an ice-free to an ice-covered Ar
ctic Ocean surface. The data were taken to observe the thermodynamic evolut
ion of a lead, a process that has previously only been accessible to measur
ement techniques confined to the lead edge. Our detailed analysis of the fi
eld data is guided by recent theoretical and experimental advances in under
standing the phase dynamics of directionally solidified alloys. Because of
the dearth of direct observations we also present time series of the releva
nt heat fluxes inferred from our data and demonstrate the controlling influ
ence that the internal phase evolution has on these quantities, We have pre
viously examined the stability of the brine trapped in a growing sea ice ma
trix both theoretically and experimentally and now find that haline convect
ion, driven from within the growing layer, is consistent with this previous
work and with the nature of direct turbulence measurements. The importance
of this process is that although ice growth is continuous, the local brine
flux commences abruptly, only after some time, in contrast. to what had pr
eviously been supposed. Hence the ice growth process itself is a source of
intermittency in oceanic boundary layer turbulence. Furthermore, we find th
at in this particular situation the sea ice growth is not simply a square r
oot function of time, in contrast to the model typically used in numerical
simulations. By far the most practical methods of studying lead convection
are numerical simulations and laboratory models, and a strong conclusion of
this study is the importance of the proper treatment of the boundary condi
tions describing the buoyancy flux.