Diorganotin(IV) derivatives of arenephosphinothiol ligands. The crystal structure of [Ph2Sn{2-Ph2P)C6H4S}(2)] and [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H3S}(2)]

Authors
Perez-Lourido, P Romero, J Garcia-Vazquez, JA Sousa, A Zubieta, J Russo, U
Citation
P. Perez-lourido et al., Diorganotin(IV) derivatives of arenephosphinothiol ligands. The crystal structure of [Ph2Sn{2-Ph2P)C6H4S}(2)] and [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H3S}(2)], J ORGMET CH, 595(1), 2000, pp. 59-65
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
595
Issue
1
Year of publication
2000
Pages
59 - 65
Database
ISI
SICI code
0022-328X(20000131)595:1<59:DDOALT>2.0.ZU;2-R
Abstract
The diorganotin complexes, [Me2Sn{2-(Ph2P)C6H4S}(2)] (1), [Ph2Sn{2-(Ph2P)C6 H4S}(2)] (2), [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H3S}(2)] (3) and [Ph2Sn{2-(Ph2PO) -6-(Me3Si)C6H4S}(2)] (4), have been prepared by reacting the corresponding diorganotin(IV) chloride with 2-(Ph2P)C6H4SH and 2-(Ph2PO)-6-(Me3Si)C6H3SH. Compound 2 crystallises in the monoclinic space group and the tin atom is tetrahedrally coordinated to two ligands acting as monodentate through the thiolate sulphur atoms. Compound 3 also crystallises in the monoclinic spac e group and, in this compound, the tin atom is octahedrically coordinated [ SnC2O2S2]. Spectral data for the complexes (IR, NMR, FAB and Mossbauer spec tra) are discussed and related to the structural information. (C) 2000 Else vier Science S.A. All rights reserved.