S. Gupta et al., The interrelationship of Cu effective charge and superconductivity in the T '-type Gd1.85-xPrxCe0.15CuOy system, J PHYS-COND, 12(1), 2000, pp. L9-L12
The lattice oxygen content (y) is measured and the effective charge (n) on
Cu is calculated for the T'-type Gd1.85-xPrxCe0.15CuOy 0.0 less than or equ
al to x less than or equal to 1.85 compounds. It is found that the supercon
ductive response (T-c onset) of the samples is related to n. Whenever n les
s than or equal to 1.87 (+/-0.01), the compounds are superconducting. The o
ptimum T-c is seen for n similar to 1.79 which is in good agreement with th
e values of n (1.77 less than or equal to n less than or equal to 1.84) cal
culated from the reported y in different optimum TcT'-cuprates. This brings
out a universality in the interrelationship between n and T-c.