The effect of configuration interaction on relativistic transition arrays

Citation
A. Bar-shalom et al., The effect of configuration interaction on relativistic transition arrays, J QUAN SPEC, 65(1-3), 2000, pp. 415-428
Citations number
16
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER
ISSN journal
00224073 → ACNP
Volume
65
Issue
1-3
Year of publication
2000
Pages
415 - 428
Database
ISI
SICI code
0022-4073(200004/05)65:1-3<415:TEOCIO>2.0.ZU;2-H
Abstract
The theory for the inclusion of configuration interaction shifts, widths an d intensity redistribution effects on relativistic transition arrays is pre sented. These effects become important when the electrostatic interaction i s strong enough, in particular for Delta n = 0 transitions. Analytic expres sions for the corrected array moments are obtained for both UTAs and STAs, bypassing the impractical need for matrix diagonalizations. Comparison of t he theoretical results with detailed calculations and with experiments are presented. (C) 2000 Elsevier Science Ltd. All rights reserved.