Hs. Lee et al., Synthesis of cyclic aza-ether compounds and studies of their use as anion receptors in nonaqueous lithium halide salts solution, J ELCHEM SO, 147(1), 2000, pp. 9-14
A series of new anion receptors, based on cyclic aza-ether compounds, have
been synthesized. The synthesis and characterization of these compounds are
described. In all these cyclic aza-ether compounds, the electron-withdrawi
ng group CF3SO2 was attached to each of the nitrogen atoms. Each member of
this class of compounds contains a different number of nitrogen atoms. When
used as additives, all of them can significantly increase the ionic conduc
tivity of lithium halide salts in tetrahydrofuran solutions due to the ion-
pair dissociation effect. This ion-pair dissociation effect is a result of
complexation between these compounds and the halide anions. Ionic conductiv
ity studies show that the complexation behavior is related to both the ring
structure of the cyclic compounds and the characteristics of the halide an
ions. X-ray diffraction data show that the diffraction patterns of the comp
lex crystals grown from cosolution of the cyclic aza-ether compound and lit
hium halide salts are completely different than those from the pure cyclic
aza-ether compounds. New Bragg peaks representing a large d-spacing (simila
r to 15 Angstrom) are observed for the complex crystals. This is clear evid
ence of the complexation between the cyclic aza-ether compound and halide a
nions. (C) 2000 The Electrochemical Society. S0013-4651 (99)04-037-9. All r
ights reserved.