Four-ball tribological apparatus was employed to investigate the sliding we
ar behavior of bearing steel 52100 treated by salt bath nitrocarburizing an
d complex nitrocarburizing processes. The microstructures, phase identifica
tion, surface hardness and hardness profiles of specimens were analyzed by
optical microscopy, X-ray diffraction and microhardness testing. The experi
mental results show that higher sub-surface hardness and hardness profiles
were obtained by nitrocarburizing and complex nitrocarburizing, although th
eir surface hardness was lower than that of commercial balls. It was also d
emonstrated that the E-phase formed on the specimen surfaces had a signific
ant effect on reducing friction coefficient but this treatment lowered the
wear resistance. Complex nitrocarburizing increased the wear resistance. Bo
th Nitrocarburizing and complex nitrocarburizing could upgrade the load-bea
ring capacity of treated specimens. (C) 2000 Elsevier Science S.A. All righ
t reserved.