Long time asymptotics are developed here for an Allen-Cahn/Cahn-Hilliard sy
stem derived recently by Cahn and Novick-Cohen [J.W. Cahn, A. Novick-Cohen,
J. Statist. Phys. 76 (1994) 877-909] as a diffuse interface model for simu
ltaneous order-disorder and phase separation. Proximity to a deep quench li
mit is assumed, and spatial scales are chosen to model Krzanowski instabili
ties in which droplets of a minor disordered phase bounded by interphase bo
undaries (LPBs) of high curvature coagulate along a slowly curved antiphase
boundaries (APBs) separating two ordered variants. The limiting motion cou
ples motion by mean curvature of the APBs with motion by minus the surface
Laplacian of the IPBs on the same timescale. Quasi-static surface diffusion
of the chemical potential occurs along APBs. The framework here yields bot
h sharp interface and diffuse interface modeling of sintering of small grai
ns and thermal grain boundary grooving in polycrystalline films. (C) 2000 E
lsevier Science B.V. All rights reserved.