Thermodynamic picture of the glassy state gained from exactly solvable models

Citation
Tm. Nieuwenhuizen, Thermodynamic picture of the glassy state gained from exactly solvable models, PHYS REV E, 61(1), 2000, pp. 267-292
Citations number
43
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
61
Issue
1
Year of publication
2000
Pages
267 - 292
Database
ISI
SICI code
1063-651X(200001)61:1<267:TPOTGS>2.0.ZU;2-U
Abstract
A picture for thermodynamics of the glassy state was introduced recently by us [Phys. Rev. Lett. 79, 1317 (1997); 80, 5580 (1998)]. It starts by assum ing that one extra parameter, the effective temperature, is needed to descr ibe the glassy state. This approach connects responses of macroscopic obser vables to a field change with their temporal fluctuations, and with the flu ctuation-dissipation relation, in a generalized, nonequilibrium way. Simila r universal relations do not hold between energy fluctuations and the speci fic heat. In the present paper, the underlying arguments are discussed in g reater length. The main part of the paper involves details of the exact dyn amical solution of two simple models introduced recently: uncoupled harmoni c oscillators subject to parallel Monte Carlo dynamics, and independent sph erical spins in a random field with such dynamics. At low temperature, the relaxation time of both models diverges as an Arrhenius law, which causes g lassy behavior in typical situations. In the glassy regime, we are able to verify the above-mentioned relations for the thermodynamics of the glassy s tate. In the course of the analysis, it is argued that stretched exponentia l behavior is not a fundamental property of the glassy state, though it may be useful for fitting in a limited parameter regime.