The origin of neutral muonium defect centers in semi-insulating GaAs has be
en studied using muon spin rotation/relaxation techniques employing alterna
ting electric fields. This technique prevents the accumulation of near-surf
ace charges which may screen the external field. Suppression of the bond-ce
ntered muonium signal with electric field suggests that muonium formation p
roceeds via transport of excess electrons from the ionization track to the
muon. The characteristic field of about 5 kV/cm may correspond to an electr
ic field induced ionization of the muon donor impurity center. (C) 1999 Pub
lished by Elsevier Science B.V. All rights reserved.