Thermochemical and sonochemical studies of adenosine-H2O-DMSO-Ca2+/K+ systems

Authors
Pandeya, JD Puri, AK Tewari, A Sharma, AK
Citation
Jd. Pandeya et al., Thermochemical and sonochemical studies of adenosine-H2O-DMSO-Ca2+/K+ systems, P I A S-CH, 111(6), 1999, pp. 747-752
Citations number
19
Categorie Soggetti
Chemistry
Journal title
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES
ISSN journal
02534134 → ACNP
Volume
111
Issue
6
Year of publication
1999
Pages
747 - 752
Database
ISI
SICI code
0253-4134(199912)111:6<747:TASSOA>2.0.ZU;2-6
Abstract
Ultrasonic, volumetric and viscometric investigations have been conducted o n adenosine base at three different temperatures 303.15, 308.15 and 313.15 K. The partial molal volume phi(nu)(0), partial molal compressibility phi(k )(0), the viscosity coefficient B of the Jones-Dole equation and the solute activation parameters Delta U, Delta S and Delta H have been calculated. A n attempt has been made to explain the changes in water structure when a co -solvent is added. Further, the results of viscosity experiments are tested in terms of transition state theory.