Radical-polar crossover reactions with a water-soluble tetrathiafulvalene derivative

Authors
Patro, B Merrett, MC Makin, SD Murphy, JA Parkes, KEB
Citation
B. Patro et al., Radical-polar crossover reactions with a water-soluble tetrathiafulvalene derivative, TETRAHEDR L, 41(3), 2000, pp. 421-424
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
3
Year of publication
2000
Pages
421 - 424
Database
ISI
SICI code
0040-4039(20000115)41:3<421:RCRWAW>2.0.ZU;2-O
Abstract
The water-soluble TTF reagent 7 undergoes the radical-polar crossover react ion in 1:1 acetone:water with a range of arenediazonium tetrafluoroborates and in water with diazonium chlorides. Purification of the reaction product s is greatly facilitated by using 7 compared with TTF. (C) 2000 Elsevier Sc ience Ltd. All rights reserved.