H. Krautscheid et F. Vielsack, [BuN(CH2CH2)(3)NBu](3)[Pb5I16] center dot 4 DMF - an iodoplumbate anion with approximately D-5h symmetry, Z ANORG A C, 626(1), 2000, pp. 3-5
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
The star-shaped anion of [BuN(CH2CH2)(3)NBu](3)-[Pb5I16]. 4DMF (1) consists
of a cyclic arrangement of five PbI6 octahedra sharing one common I atom i
n the centre of an almost planar Pb-5 ring. Compound 1 crystallizes in spac
e group P2(1) with a = 1657.2(1), b = 2029.2(1), c = 1773.6(1) pm, beta = 1
13.238(8)degrees, Z = 2.