[BuN(CH2CH2)(3)NBu](3)[Pb5I16] center dot 4 DMF - an iodoplumbate anion with approximately D-5h symmetry

Citation
H. Krautscheid et F. Vielsack, [BuN(CH2CH2)(3)NBu](3)[Pb5I16] center dot 4 DMF - an iodoplumbate anion with approximately D-5h symmetry, Z ANORG A C, 626(1), 2000, pp. 3-5
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
1
Year of publication
2000
Pages
3 - 5
Database
ISI
SICI code
0044-2313(200001)626:1<3:[CD4D->2.0.ZU;2-4
Abstract
The star-shaped anion of [BuN(CH2CH2)(3)NBu](3)-[Pb5I16]. 4DMF (1) consists of a cyclic arrangement of five PbI6 octahedra sharing one common I atom i n the centre of an almost planar Pb-5 ring. Compound 1 crystallizes in spac e group P2(1) with a = 1657.2(1), b = 2029.2(1), c = 1773.6(1) pm, beta = 1 13.238(8)degrees, Z = 2.