Synthesis of GaN-carbon composite nanotubes and GaN nanorods by arc discharge in nitrogen atmosphere

A method using an arc discharge in a nitrogen atmosphere for synthesizing l arge quantities of gallium nitride (GaN)-Carbon composite nanotubes and GaN nanorods is reported. The reaction is achieved by a dc arc discharge betwe en a graphite anode filled with a mixture of GaN, graphite, and nickel powd ers and a graphite cathode in a nitrogen atmosphere. The GaN are presented as rodlike fillings in the composite tubes and the isolated GaN nanorods ha ve diameters in the range of 7-45 nanometers and a length of up to 40 mu m. The outer graphitic shells of the composite carbon nanotubes have thicknes ses ranging from 1 to 8 nm. It was found that the use of a nitrogen atmosph ere plays a crucial role for the growth of the GaN nanorods fillings and th e individual GaN nanorods. (C) 2000 American Institute of Physics. [S0003-6 951(00)02905-3].