Photoswitchable trinuclear transition-metal complexes. Intramolecular triplet-triplet energy transfer from fac-(diimine)Re-I(CO)(3) chromophores to astilbene-like bridging ligand

Authors
Sun, SS Robson, E Dunwoody, N Silva, AS Brinn, IM Lees, AJ
Citation
Ss. Sun et al., Photoswitchable trinuclear transition-metal complexes. Intramolecular triplet-triplet energy transfer from fac-(diimine)Re-I(CO)(3) chromophores to astilbene-like bridging ligand, CHEM COMMUN, (3), 2000, pp. 201-202
Citations number
20
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
3
Year of publication
2000
Pages
201 - 202
Database
ISI
SICI code
1359-7345(2000):3<201:PTTCIT>2.0.ZU;2-P
Abstract
A series of novel trinuclear metal complexes containing fac-(diimine)Re-I(C O)(3) chromophores and a stilbene-like bridging ligand have been synthesize d and in CH3CN exhibit photoswitchable luminescence arising from photoinduc ed intramolecular energy transfer from the fac-(diimine)-Re(CO)(3) chromoph ores to the bridging ligand.