The room-temperature crystallisation of a one-dimensional gallium fluorophosphate, Ga(HPO4)(2)F center dot H3N(CH2)(3)NH3 center dot 2H(2)O, a precursor to three-dimensional microporous gallium fluorophosphates

Authors
Walton, RI Millange, F Le Bail, A Loiseau, T Serre, C O'Hare, D Ferey, G
Citation
Ri. Walton et al., The room-temperature crystallisation of a one-dimensional gallium fluorophosphate, Ga(HPO4)(2)F center dot H3N(CH2)(3)NH3 center dot 2H(2)O, a precursor to three-dimensional microporous gallium fluorophosphates, CHEM COMMUN, (3), 2000, pp. 203-204
Citations number
20
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
3
Year of publication
2000
Pages
203 - 204
Database
ISI
SICI code
1359-7345(2000):3<203:TRCOAO>2.0.ZU;2-T
Abstract
The one-dimensional gallium fluorophosphate Ga(HPO4)(2)F . H3N(CH2)(3)NH3. 2H(2)O 1 crystallises at room temperature from an aqueous mixture of Ga2O3, H3PO4, 1,3-diaminopropane, and HF; compound 1 converts to the three-dimens ional microporous fluorophosphate ULM-3 on heating to 160 degrees C under h ydrothermal conditions.