Clusters containing metal-metal bonds linking high- and low-valent metal centres: synthesis and structure of Ru-3(CO)(12){Mo(NAr)(2)}

Authors
Ali, S Carty, AJ Deeming, AJ Enright, GD Hogarth, G
Citation
S. Ali et al., Clusters containing metal-metal bonds linking high- and low-valent metal centres: synthesis and structure of Ru-3(CO)(12){Mo(NAr)(2)}, CHEM COMMUN, (2), 2000, pp. 123-124
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
2
Year of publication
2000
Pages
123 - 124
Database
ISI
SICI code
1359-7345(2000):2<123:CCMBLH>2.0.ZU;2-F
Abstract
Room temperature reaction of K-2[Ru-3(CO)(11)] with the molybdenum(VI) bis( imido) complexes Mo(NAr)(2)Cl-2(dme) (Ar = C6H3X2-2,6; X = Me, Pr-i, Cl; dm e = 1,2-dimethoxyethane) affords new high-low valent clusters Ru-3(CO)(12){ Mo(NAr)(2)} which adopt a butterfly arrangement of metal centres with [Ru-3 (CO)(12)](2-) acting as a ligand at a molybdenum(VI) centre.