M. Yoshida et al., Catalytic production of urethanes from amines and alkyl halides in supercritical carbon dioxide, CHEM COMMUN, (2), 2000, pp. 151-152
Some common onium salts catalysed selective urethane production from amines
and alkyl halides in supercritical carbon dioxide, which acted not only as
an alternative to organic solvents but also as a phosgene replacement; the
reaction efficiency was 50-100 times higher than that attained in heptane.