Keggin unit supported transition metal complexes: hydrothermal synthesis and characterization of [Ni(2,2 '-bipy)(3)](1.5)[PW12O40Ni(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O and [Co(1,10 '-phen)(3)](1.5)[PMo12O40Co(1,10 '-phen)(2)(H2O)]center dot 0.5H(2)O

Authors
Xu, Y Xu, JQ Zhang, KL Zhang, Y You, XZ
Citation
Y. Xu et al., Keggin unit supported transition metal complexes: hydrothermal synthesis and characterization of [Ni(2,2 '-bipy)(3)](1.5)[PW12O40Ni(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O and [Co(1,10 '-phen)(3)](1.5)[PMo12O40Co(1,10 '-phen)(2)(H2O)]center dot 0.5H(2)O, CHEM COMMUN, (2), 2000, pp. 153-154
Citations number
21
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
2
Year of publication
2000
Pages
153 - 154
Database
ISI
SICI code
1359-7345(2000):2<153:KUSTMC>2.0.ZU;2-9
Abstract
Two new Keggin unit supported transition metal complexes, [Ni(2,2'-bipy)(3) ](1.5)[PW12O40Ni(2,2'-bipy)(2)(H2O)]. 0.5H(2)O 1 and [Co(1,10'-phen)(3)](1. 5)[PMo12O40Co(1,10',-phen)(2)- (H2O)]. 0.5H(2)O 2, are synthesized by a hyd rothermal method; complex 1 is characterized by X-ray crystallography, show ing that the [Ni(2,2'-bipy)(2)(H2O)](2+) units are covalently bonded to the alpha-Keggin cluster [PW2V- (W10O40)-O-VI](5-).