Hf27Si6P10, a novel metal-rich compound with P-2 groups

Citation
Cc. Huang et al., Hf27Si6P10, a novel metal-rich compound with P-2 groups, CHEM COMMUN, (1), 2000, pp. 17-18
Citations number
34
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
1
Year of publication
2000
Pages
17 - 18
Database
ISI
SICI code
1359-7345(2000):1<17:HANMCW>2.0.ZU;2-V
Abstract
The new ternary metal rich compound Hf27Si6P10 has been synthesized by redu ction of HfP with Hf and Si; Hf27Si6P10 crystallizes in a new structure typ e, a characteristic and unexpected feature of which is the presence of P-2 groups; the structural results are interpreted with the aid of high-level b and structure calculations.