The article deals with the problem of preparing single crystals of anhydrou
s sulphates of amphoteric metals lead and tin. It gives a comprehensive rev
iew on up to date recent knowledge on the chemical and physical properties
of these sulphates and, in addition, it describes some methods of preparing
their pure anhydrous form. It also informs about the experiments of single
crystal growth. It draws attention to several possibilities of the solutio
n of this problem, which is still not satisfactorily solved.