B. Chowdhury, FUNCTIONAL-EVALUATION OF A LIQUID-MOLDING 2-COMPONENT COMBINATION RESIN - STUDY OF AN ADVANCED MATERIAL, Journal of thermal analysis, 49(1), 1997, pp. 325-334
Functional parameters contributing to the recognizable good performanc
e of a highly crosslinked olefinic polymer based on cyclopentadiene ha
ve been evaluated by a limited range of stress decay and creep recover
y from a fixed deformation over constant time periods. The experimenta
l design for these involved a calculated stress (load) at the initial
sample deformation (displacement) for determination of changes in stre
ss in bending mode and flex creep under applied load at three constant
temperature segments of 6 h each with 20 min recovery time between se
gments. The results have identified a behavior which is typical of int
erfacial orientational effect in a two-component system. Thermal condu
ctivity, heat capacity and density at the same temperatures were measu
red for determination of variations in thermal diffusivity as an indic
ation of the competing effects of densification and thermal expansion
fbr such a system. Static charging and polarization experiments were p
erformed for evaluation of other desired uses of this material, in mov
ing parts and in direct or induced voltage applications. The latter al
lows measurement of dynamic charge transport through the resin matrix.
Calculations indicate generation of charge carriers from weak seconda
ry bonding typical of polymer interfaces. The polarization itself cons
ists of dipole orientation characterized by relatively high activation
energy. The intrinsic mechanical properties for this material had bee
n determined by the manufacturer, but the performance parameters repor
ted in this study have been determined for the first time for explorat
ion of further uses for this material.