R. Stringer et al., Concentrations of phthalate esters and identification of other additives in PVC children's toys, ENV SCI P R, 7(1), 2000, pp. 27-36
This study was intended to provide data on the composition of soft PVC toys
, addressing the widest practicable range of chemical additives and includi
ng non-phthalate additives. The study also included toys from as many count
ries as possible, since for many, no data were available. A total of 72 toy
s were purchased in 17 countries. The majority (64) were PVC or had PVC sec
tions. in almost all the soft PVC toys analysed, phthalates comprised a siz
eable proportion (most frequently 10-40%) of the total weight of the toy.
The predominant phthalates detected were diisononyl phthalate (DINP) and di
(2-ethylhexyl) phthalate (DEHP). Other phthalates identified in high concen
trations in some toys include isomeric mixes of diisooctyl phthalate (DIOP)
and diisodecyl phthaiate (DIDP). The estrogenic chemical nonylphenol was i
solated from 13 toys, while 2 toys were found to contain the fungicide Fung
itrol 11 (Folpet). 78% of PVC toys contained one or more extractable organi
c compounds in addition to those reported above.