Structure of diaquatetrakis(iso-pyridinopropionato) dicopper(II) perchlorate; [Cu(C5H5N(Me)CHCOO)(2)(H2O)](2) (ClO4)(4)

Authors
Wu, H Gu, SX Yin, GQ Dong, RW Zeng, FL
Citation
H. Wu et al., Structure of diaquatetrakis(iso-pyridinopropionato) dicopper(II) perchlorate; [Cu(C5H5N(Me)CHCOO)(2)(H2O)](2) (ClO4)(4), I J CHEM A, 38(10), 1999, pp. 1057-1059
Citations number
13
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
38
Issue
10
Year of publication
1999
Pages
1057 - 1059
Database
ISI
SICI code
0376-4710(199910)38:10<1057:SODDP>2.0.ZU;2-Y
Abstract
Diaquatetrakis-(iso-pyridinopropionato) dicopper(II) perchlorate, [Cu(C5H5 N(Me)CHCOO)(2)(H2O)](2). (ClO4)(4), Mr = 1165.5, orthorhombic, Pbca, a = 15 .608(2), b = 19.209(2), c = 15.707(2)Angstrom, V = 4708.8 Angstrom(3), Z = 4, Dm = 1.64g cm(-3), Dx = 1.62g cm(-3), lambda(Cu K alpha) = 1.54184 Angst rom, mu = 40.4(cm(-1)), F(000) = 2367, T = 293K, R = 0.067, wR = 0.083 and S = 3.46 for 2968 observed reflections [I>3 sigma(I-0)] has been prepared a nd characterised by X-ray analysis. The structure consists of discrete dinu clear, [Cu(i-ppBET)(2)(H2O)](2)(4+) cations and four independent (ClO4)(-) anions. Each Cu2+ is five-coordinate with four carboxylato O atoms and an a qua ligand.