A novel synthesis of hexakis(trifluoromethyl)cyclotriphosphazene. Single-crystal X-ray structures of N3P3(CF3)(6) and N3P3F6

Authors
Singh, RP Vij, A Kirchmeier, RL Shreeve, JM
Citation
Rp. Singh et al., A novel synthesis of hexakis(trifluoromethyl)cyclotriphosphazene. Single-crystal X-ray structures of N3P3(CF3)(6) and N3P3F6, INORG CHEM, 39(2), 2000, pp. 375-377
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
2
Year of publication
2000
Pages
375 - 377
Database
ISI
SICI code
0020-1669(20000124)39:2<375:ANSOHS>2.0.ZU;2-C
Abstract
Reaction of hexafluorocyclotriphosphazene (N3P3F6) With trimethyl(trifluoro methyl)silane in the presence of a catalytic amount of cesium fluoride in T HF produced hexakis(trifluoromethyl)cyclotriphosphaze [N3P3(CF3)(6)] in 90% isolated yield. N3P3(CF3)(6) is fully characterized by melting point, IR, NMR (F-19,C-13, (31)p), MS, and elemental analysis data. Single-crystal X-r ay structures of N3P3(CF3)(6) and N3P3F6 are reported.