Authors
Citation
D. Britton et K. Emerson, Crystal structure of tetrachlorobis [mu-imidocarbonylchloridato]diboron, J CHEM CRYS, 29(7), 1999, pp. 841-843
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542
→ ACNP
Volume
29
Issue
7
Year of publication
1999
Pages
841 - 843
Database
ISI
SICI code
1074-1542(199907)29:7<841:CSOT[>2.0.ZU;2-2
Abstract
Boron trichloride and mercuric cyanide react slowly to form the title compo
und, B2N2C2Cl8, which contains a four-membered B2N2 ring with alternating B
Cl2 and N = CCl2. Crystals are triclinic, space group Pi, a = 6.1198(1), b
= 7.4457(3), c = 7.9186(3) Angstrom, alpha = 117.064(2), beta = 106.923, ga
mma = 93.712(2)degrees, Z = 1, and V = 299.07(2) Angstrom(3). The compound
has a crystallographic center of symmetry but the metric symmetry is close
to the expected mmm.