A nonequilibrium ensemble formalism: Criterion for truncation of description

Citation
Jg. Ramos et al., A nonequilibrium ensemble formalism: Criterion for truncation of description, J CHEM PHYS, 112(6), 2000, pp. 2692-2700
Citations number
50
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
112
Issue
6
Year of publication
2000
Pages
2692 - 2700
Database
ISI
SICI code
0021-9606(20000208)112:6<2692:ANEFCF>2.0.ZU;2-H
Abstract
In the framework of a nonequilibrium statistical ensemble formalism, consis ting of the so-called Nonequilibrium Statistical Operator Method, we discus s the question of the choice of the space of thermohydrodynamic states. We consider in particular the relevant question of the truncation of descripti on (reduction of the dimension of the state space). A criterion for justify ing the different levels of truncation is derived. It depends on the range of wavelengths and frequencies which are the relevant ones for the characte rization, in terms of normal modes, of the thermohydrodynamic motion in a n onequilibrium open system. Applications to the cases of thermal-sensitive r esins and of n-doped polar semiconductors are done, numerical results are p resented, and experimental observation is discussed. (C) 2000 American Inst itute of Physics. [S0021-9606(00)50705-3].