Probe measurements were performed in the flow field produced by inject
ion of helium or air into a supersonic airstream. The injectant was se
eded with water and Rayleigh scattering was used to image the injectan
t plume. The region of the flow containing injectant-air mixture is se
en to be highly unsteady, leading to the intermittent presence of inje
ctant in certain regions. The intermittency is inferred. It is shown t
hat bias errors can occur when the probe data is analyzed by technique
s which assume steady flow. A technique for relatively bias-free analy
sis utilizing the intermittency measurements is presented and the bias
errors are estimated. The gas-sampling probe is shown to measure the
mass-weighted-mean mass fraction of helium, which is significantly les
s than the simple mean. ii new measure of mixing efficiency obtained f
rom the combined probe and intermittency measurements is discussed.