Mavr. Da Silva et al., Standard molar enthalpy of formation of 4-iodobenzoic acid by static and rotating-bomb calorimetry, J CHEM THER, 31(12), 1999, pp. 1635-1641
The standard (p(o) = 0.1 MPa) molar enthalpy of combustion of 4-iodobenzoic
acid, at T = 298.15 K, was measured by static-bomb and rotating-bomb calor
imetry, from which the standard molar enthalpy of formation, in the crystal
line state, was derived.
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The values obtained confirm that 4-iodobenzoic acid is a satisfactory test
substance for combustion of organo-iodine compounds. Using a literature val
ue for its standard molar enthalpy of sublimation, the standard molar entha
lpy of formation, in the gaseous state, was also derived and compared with
an estimate by means of structural contributions. (C) 1999 Academic Press.