The preferred conformation of alpha-fluoroamides

Authors
Banks, JW Batsanov, AS Howard, JAK O'Hagan, D Rzepa, HS Martin-Santamaria, S
Citation
Jw. Banks et al., The preferred conformation of alpha-fluoroamides, J CHEM S P2, (11), 1999, pp. 2409-2411
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
ISSN journal
03009580 → ACNP
Issue
11
Year of publication
1999
Pages
2409 - 2411
Database
ISI
SICI code
0300-9580(199911):11<2409:TPCOA>2.0.ZU;2-P
Abstract
X-Ray structures of two alpha-fluoroamide derivatives show the O=C-C-F moie ty tending towards a trans planar conformation, for which ab initio calcula tions suggest a deep (up to 8 kcal mol(-1)) potential minimum.