Copolymerization of CO2 and 1,2-cyclohexene oxide using a CO2-soluble chromium porphyrin catalyst

The copolymerization of 1,2-cyclohexene oxide (CHO) with carbon dioxide was performed, using supercritical carbon dioxide (scCO(2)) as both solvent an d reactant, to produce an aliphatic polycarbonate. A CO2-soluble catalyst, tetra(pentafluorophenyl)porphyrin chromium(III) chloride (CrTFPPCl), was sy nthesized and used to catalyze the polymerization in the presence of 4-(dim ethylamino)pyridine (DMAP) as cocatalyst. The best yields for the copolymer ization (up to similar to 75%) were obtained in the temperature range 95-11 0 degrees C over a period of 18 h, with a molar ratio of catalyst to monome r of 2.6 x 10(-3). High catalyst efficiencies (3.9 kg of polymer/g of Cr) w ere observed under these conditions. The copolymers consisted predominantly of carbonate linkages (90-97%), and the chain microstructure was analyzed by H-1 NMR and C-13 NMR spectroscopy. Gel permeation chromatography reveale d number-average molecular weights (M-n) of the order of 3500. In contrast to previous studies involving supercritical CO2, narrow polymer molecular w eight distributions were observed throughout (M-w/M-n < 1.4).