H. Sato et al., Characterization of chitin-based polymer hybrids by temperature-programmedanalytical pyrolysis techniques. 2. Chitin-graft-poly(2-methyl-2-oxazoline)/poly(vinyl alcohol) blends, MACROMOLEC, 33(2), 2000, pp. 357-362
Chitin-graft-poly(2-methyl-2-oxazoline)/poly(vinyl alcohol) (PVA) blends we
re characterized by means of analytical pyrolysis techniques such as temper
ature-programmed pyrolysis-mass spectrometry (TPPy-MS), TPPy-gas chromatogr
aphy (TPPY-GC) and Py-GC mainly in terms of their miscibility and the site
of the intermolecular interaction. The thermal degradation of the chitin de
rivative/PVA Mends took place apparently in two stages reflecting the degra
dation of both constituent polymers. However, peak-top temperatures for bot
h degradation stages changed as a function of blend composition; the first
degradation stage, mostly corresponding to the dehydration of PVA, shifted
to higher temperatures when the chitin derivative content is increased in t
he blend. Although the yields of 2-butenal from the PVA moiety increased by
blending the chitin derivative, those of acetamide and N-ethylacetamide fr
om the chitin derivative moiety exhibit an opposite trend. These temperatur
e-shifts and the variations in the yields of the pyrolysis products suggest
ed that intermolecular interactions might be contributing to a differing ex
tent as a function of the blend composition. Moreover, the observed degrada
tion behaviors for the chitin derivative/PVA blends showed the opposite tre
nd for the case of the chitin derivative/PVC blend system previously invest
igated. Thus, the observed degradation mechanisms of this blend system were
discussed by comparison with those for the chitin derivative/PVC blend sys
tem.