A review of the contributions of the atom probe field-ion microscopy (APFIM
) technique to the microstructural characterization of pressure vessel stee
ls and to the understanding of the embrittlement of these materials during
neutron irradiation is presented. Atom probe studies have revealed that the
microstructure contains a variety of ultrafine clusters and precipitates s
ome of which are only formed during neutron irradiation. Furthermore, there
is a complex pattern of segregation of various solutes (including phosphor
us, nickel, manganese, or molybdenum) to grain boundaries in some pressure
vessel materials, and there may also be additional intergranular precipitat
ion in these materials. Published by Elsevier Science inc.