Diamondoid hydrocarbon ratios as indicators of biodegradation in Australian crude oils

The effect of biodegradation on diamondoid distributions in petroleum has b een investigated on a series of crude oils reservoired in two Australian se dimentary basins, the Gippsland Basin and the Carnarvon Basin. The ratio of methyladamantanes to adamantane rises with increasing biodegradation. Sign ificant changes in the ratio occur at extreme levels, indicating that diamo ndoids can be indicators of petroleum biodegradation especially when most o ther hydrocarbons have been removed. The methyladamantane/adamantane ratio can also be used to assess the composition of crude oils that are comprised of a mixture of severely biodegraded and non-biodegraded oil. (C) 2000 Els evier Science Ltd. All rights reserved.